Narrative:

Descending through FL330 the 'air duct overheat' caution light illuminated. The appropriate checklist was run but had no effect on correcting the problem. The cabin and cockpit were soon enveloped by a strong; acrid; burning odor at which time we declared an emergency and executed a rapid descent while requesting the closest airport. ATC vectored us to an ILS approach at ZZZ. We landed the aircraft and evacuate/evacuationed by normal egress without further incident.

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Original NASA ASRS Text

Title: CITATION C525 CREW HAS FUMES IN COCKPIT AND CABIN; DECLARES AN EMER AND LANDS.

Narrative: DSNDING THROUGH FL330 THE 'AIR DUCT OVERHEAT' CAUTION LIGHT ILLUMINATED. THE APPROPRIATE CHKLIST WAS RUN BUT HAD NO EFFECT ON CORRECTING THE PROB. THE CABIN AND COCKPIT WERE SOON ENVELOPED BY A STRONG; ACRID; BURNING ODOR AT WHICH TIME WE DECLARED AN EMER AND EXECUTED A RAPID DSCNT WHILE REQUESTING THE CLOSEST ARPT. ATC VECTORED US TO AN ILS APCH AT ZZZ. WE LANDED THE ACFT AND EVACED BY NORMAL EGRESS WITHOUT FURTHER INCIDENT.

Data retrieved from NASA's ASRS site as of January 2009 and automatically converted to unabbreviated mixed upper/lowercase text. This report is for informational purposes with no guarantee of accuracy. See NASA's ASRS site for official report.