Narrative:

Extreme cold cockpit temperatures were experienced enroute from ZZZ to ZZZ1 airport with two crew and four passengers on board.the crew begin to notice cold cockpit temperatures 30 minutes after departure from ZZZ airport. The crew attempted to warm the cockpit temperature by increasing the controller knob. This had no effect on the actual cockpit temp; a further increase to the temp controller was made. This induced the duct 2 overtemp cas. The crew followed the checklist for the corresponding cas massage and the cas message extinguished. Yet the cockpit temperature continued to decrease. The crew begins to experience adverse effects from the cold temperatures inside the cockpit. Realizing the adverse effects the extreme cold temperatures were having; the crew [notified ATC] and requested an immediate emergency descent to a lower altitude and requested a divert to ZZZ2 airport.the descent; approach and landing at ZZZ2 was safe and uneventful. Heavily corroded tmvs (temperature modulating valves) were found after maintenance was performed the following day.

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Original NASA ASRS Text

Title: EMB-505 flight crew reported the loss of temperature control led to a diversion where maintenance found corroded Temperature Modulating Valves.

Narrative: Extreme cold cockpit temperatures were experienced enroute from ZZZ to ZZZ1 airport with two crew and four passengers on board.The crew begin to notice cold cockpit temperatures 30 minutes after departure from ZZZ airport. The crew attempted to warm the cockpit temperature by increasing the controller knob. This had no effect on the actual cockpit temp; a further increase to the temp controller was made. This induced the duct 2 OVERTEMP CAS. The crew followed the checklist for the corresponding CAS massage and the CAS message extinguished. Yet the cockpit temperature continued to decrease. The crew begins to experience adverse effects from the cold temperatures inside the cockpit. Realizing the adverse effects the extreme cold temperatures were having; the crew [notified ATC] and requested an immediate emergency descent to a lower altitude and requested a divert to ZZZ2 airport.The descent; approach and landing at ZZZ2 was safe and uneventful. Heavily corroded TMVs (Temperature Modulating Valves) were found after maintenance was performed the following day.

Data retrieved from NASA's ASRS site and automatically converted to unabbreviated mixed upper/lowercase text. This report is for informational purposes with no guarantee of accuracy. See NASA's ASRS site for official report.