Narrative:

I leveled off at approximately 14;000 ft on an IFR flight plan. As soon as I started to make my power adjustments from climb to cruise I had a loud knocking sound followed by an immediate loss of all manifold pressure. I declared an emergency with center and diverted directly to ZZZ. On the descent there was thick smoke in the cockpit and I had to open the windows for ventilation. We landed without incident without power. I am not sure what caused the problem; but think that it might have been a bad valve or cylinder.

Google
 

Original NASA ASRS Text

Title: C210 pilot made a dead stick landing following an engine failure.

Narrative: I leveled off at approximately 14;000 FT on an IFR flight plan. As soon as I started to make my power adjustments from climb to cruise I had a loud knocking sound followed by an immediate loss of all manifold pressure. I declared an emergency with Center and diverted directly to ZZZ. On the descent there was thick smoke in the cockpit and I had to open the windows for ventilation. We landed without incident without power. I am not sure what caused the problem; but think that it might have been a bad valve or cylinder.

Data retrieved from NASA's ASRS site as of April 2012 and automatically converted to unabbreviated mixed upper/lowercase text. This report is for informational purposes with no guarantee of accuracy. See NASA's ASRS site for official report.