Narrative:

After beginning an initial descent from FL430 and passing through (around) FL400; the flight crew noticed fumes and smoke accumulating in the cockpit and cabin. An emergency descent was immediately initiated with appropriate memory items and checklist completed. ATC was notified and vectors to a suitable airport were given. After passing through (around) FL200 the smoke and fumes rapidly dissipated and a normal landing was made with no further incident. [We needed a] replacement of a malfunctioning cockpit temperature control valve and replacement of the ecs temperature controller. I also informed [FSDO] that there was no evidence of a fire.

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Original NASA ASRS Text

Title: A LR45 cockpit filled with smoke and fumes as it began a descent so the crew declared an emergency and diverted. A cockpit temperature control valve and environmental control system (ECS) temperature controller were replaced.

Narrative: After beginning an initial descent from FL430 and passing through (around) FL400; the flight crew noticed fumes and smoke accumulating in the cockpit and cabin. An emergency descent was immediately initiated with appropriate memory items and checklist completed. ATC was notified and vectors to a suitable airport were given. After passing through (around) FL200 the smoke and fumes rapidly dissipated and a normal landing was made with no further incident. [We needed a] replacement of a malfunctioning cockpit temperature control valve and replacement of the ECS temperature controller. I also informed [FSDO] that there was no evidence of a fire.

Data retrieved from NASA's ASRS site as of April 2012 and automatically converted to unabbreviated mixed upper/lowercase text. This report is for informational purposes with no guarantee of accuracy. See NASA's ASRS site for official report.